METHOD OF SYNTHESIS OF APPLIED CATALYST USED FOR GAS-PHASE POLYMERIZATION OF ETHYLENE AND COPOLYMERIZATION OF ETHYLENE WITH α-OLEFINS Russian patent published in 1994 - IPC

Abstract RU 2007424 C1

FIELD: organic chemistry. SUBSTANCE: solution of organomagnesium compound of the general formula , where R′=C2H5, i=C4H9, R″=н=C4H9, i=C5H11; a = 0,01-0,1; b = 0,5-2,0, in chloro- benzene is interacted with CCl4 at mole ratio CCl4/Mg = 3-5 at 50-70 C following by treatment of solid product formed with solution of ethylaluminium chloride of the general formula (ElAlCl2,El2AlCl,El3Al2Cl3) and then - with solution of TiCl4 or VOCl3 at mole ratio Al/Mg = 0,5-2,0 and Ti(V)/Mo= 0,01-0,1 at 20-60 C. Method is used for synthesis of catalyst. EFFECT: improved method of synthesis. 1 tbl

Similar patents RU2007424C1

Title Year Author Number
METHOD OF PRODUCTION OF SUPPORTED CATALYST USING FOR SUSPENSION POLYMERIZATION OF ETHYLENE AND α-OLEFINS 1990
  • Makhtarulin S.I.
  • Zakharov V.A.
  • Mikenas T.B.
  • Sergeev S.A.
  • Khmelinskaja A.D.
  • Nikitin V.E.
  • Grigor'Ev V.A.
  • Zlotnikov L.M.
  • Ivanchev S.S.
  • Perkovets M.V.
RU1732536C
METHOD TO PRODUCE APPLIED CATALYST FOR ETHYLENE POLYMERIZATION AND COPOLYMERIZATION OF ETHYLENE WITH ALFA-OLEFINS 1994
  • Zakharov V.A.
  • Makhtarulin S.I.
  • Sergeev S.A.
  • Mikenas T.B.
  • Nikitin V.E.
  • Echevskaja L.G.
  • Khmelinskaja A.D.
RU2064836C1
METHOD OF PREPARING CATALYST FOR POLYMERIZATION OF ETHYLENE AND COPOLYMERIZATION THEREOF WITH ALPHA-OLEFINS 1985
  • Ivanova T.M.
  • Zakharov V.A.
  • Nikitin V.E.
  • Sever A.V.
  • Echevskaja L.G.
  • Petrov Ju.M.
  • Kozhanov S.N.
  • Leont'Ev V.A.
SU1317740A1
ETHYLENE POLYMERIZATION CATALYST AND METHOD OF PREPARATION THEREOF 1985
  • Zakharov V.A.
  • Mikenas T.B.
  • Makhtarulin S.I.
  • Nikitin V.E.
  • Smolin S.V.
  • Ivanova T.M.
  • Tolstov G.P.
  • Kajmashnikov V.M.
  • Gomenjuk V.Ja.
  • Balashov V.V.
  • Ivanchev S.S.
  • Grigor'Ev V.A.
  • Korotkov S.I.
SU1269330A1
PREPARATION OF ETHYLENE POLYMERIZATION CATALYST 1982
  • Makhtarulin S.I.
  • Sergeev S.A.
  • Zakharov V.A.
  • Nikitin V.E.
  • Khmelinskaja A.D.
  • Sappaev M.S.
  • Tolstov G.P.
  • Kajmashnikov V.M.
  • Balashov V.V.
  • Shishlov S.S.
SU1053352A1
METHOD OF PRODUCING CATALYST FOR POLYMERISATION OF ETHYLENE AND COPOLYMERISATION OF ETHYLENE WITH ALPHA-OLEFINS 2014
  • Mikenas Tat'Jana Borisovna
  • Nikitin Valentin Evgen'Evich
  • Zakharov Vladimir Aleksandrovich
RU2570645C1
METHOD OF PREPARING APPLIED CATALYST FOR ETHYLENE POLYMERIZATION AND COPOLYMERIZATION OF ETHYLENE WITH α-OLEFINS 1993
  • Zakharov V.A.
  • Mikenas T.B.
  • Echevskaja L.G.
  • Makhtarulin S.I.
RU2047355C1
CATALYST PREPARATION PROCESS AND ETHYLENE POLYMERIZATION AND ETHYLENE-ALPHA-OLEFIN COPOLYMERIZATION PROCESSES UTILIZING THIS CATALYST 2004
  • Nikitin V.E.
  • Mikenas T.B.
  • Zakharov V.A.
RU2257263C1
PREPARATION OF ETHYLENE POLYMERIZATION CATALYST 1985
  • Zakharov V.A.[Su]
  • Nikitin V.E.[Su]
  • Mikenas T.B.[Su]
  • Makhtarulin S.I.[Su]
  • Ermakov Ju.I.[Su]
  • Smolin S.V.[Su]
  • Khmelinskaja A.D.[Su]
  • Gans-Diter Fogt[Dd]
  • Khartmut Brederek[Dd]
  • Leander Osval'D[Dd]
  • Khel'Mut Vendler[Dd]
  • Grigor'Ev V.A.[Su]
  • Ivanchev S.S.[Su]
  • Korotkov S.I.[Su]
SU1460792A1
METHOD OF OBTAINING VANADIUM-MAGNESIUM CATALYST OF ETHYLENE POLYMERISATION AND COPOLYMERISATION OF ETHYLENE WITH ALPHA-OLEFINS 2012
  • Mikenas Tat'Jana Borisovna
  • Zakharov Vladimir Aleksandrovich
  • Nikitin Valentin Evgen'Evich
RU2502560C1

RU 2 007 424 C1

Authors

Makhtarulin S.I.

Zakharov V.A.

Sergeev S.A.

Mikenas T.B.

Echevskaja L.G.

Ven'Jaminov A.S.

Dates

1994-02-15Published

1990-04-20Filed