FIELD: organoaluminium compounds. SUBSTANCE: product: new organoaluminium compound 1,4-bis[(dialkoxy)aluma]-trans-2,3-dialkylbutanes of the formula where R R=C2H5 or C4H9; R′=C3H7, C4H9 or C5H11. 1,4-Bis-[(dialkoxy)aluma] -trans-2,3-dialkylbutanes were synthesized by interaction of α-olefins (1-hexene, 1-heptene, 1-octene) with dialkoxyaluminium chloride of the formula (RO)2AlCl where R R=(C2H5-C4H9) and metallic magnesium at the molar ratio (20-22):(20-22):10 in the presence of (C5H5)2ZrCl2 at concentration 2-6 mole% in argon atmosphere, at the room temperature, under normal pressure in tetrahydrofuran, at stirring for 8-12 hr. The yield is 66-84% Synthesized compounds can be used in the processes of polymerization and oligomerization of olefin and diene hydrocarbons. EFFECT: improved method of synthesis, increased yield. 1 tbl
Title | Year | Author | Number |
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METHOD OF SYNTHESIS OF 1,4-BIS [N,N-DIALKYLAMINE) ALUMINO] -TRANS-2,3-DIALKYLBUTANES | 1992 |
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RU2039751C1 |
METHOD OF SYNTHESIS OF 1,4-BIS-(DIALKYLALUMINO)-TRANS-2,3-DIALKYLBUTANES | 1992 |
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METHOD OF PREPARING 1,2-BIS(DIALKYLALUMA)CIS-1,2-DIPHENYL (ALKYL)ETHYLENES | 1996 |
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METHOD FOR PRODUCING TRANS-3,4- DI(SUBSTITUTED)TETRAHYDROTHIO-PHENES | 1993 |
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METHOD OF PREPARING 1,2-BIS(DIALKYLALUMA)-1- PHENYL(ALKYL)ETHANES | 1996 |
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METHOD OF SYNTHESIS OF 1-ETHYL-2,3-DIPHENYL(ALKYL)ALUMACYCLO-PROPENES | 1996 |
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METHOD OF PREPARING DI(ALUMINIUM DIETHYL) [60] FULLERENES | 1999 |
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Authors
Dates
1995-11-20—Published
1992-06-23—Filed