METHOD OF PREPARATION OF VINYL ALCOHOL COPOLYMERS Russian patent published in 1997 - IPC

Abstract RU 2090572 C1

FIELD: oil refining industry, textile and other industries. SUBSTANCE: method is carried out by copolymerization of vinyl acetate with glycidyl ether in methane by initiating azobisisobutyric acid followed by alkaline alcoholysis in the presence of NaOH, squeezing the suspension and drying the product, 99.5-98 wt parts of vinyl acetate 0.5-2 wt parts of ethylene glycol glycidyl ether and 0.5-2 wt parts of urea are polymerized in the presence of methanol of asobisisobutyric acid dinitrile. The final polymer solution is diluted with methanol and saponified in the presence of NaOH. Vinyl alcohol suspension is neutralized with acetic acid. Squeezed, weight fraction of acetate groups in the polymer is gel-like composition. EFFECT: more efficient preparation method. 2 cl, 1 tbl

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RU 2 090 572 C1

Authors

Arakelov Georgij Gurgenovich[Am]

Nalbandjan Jurij Ezekovich[Am]

Gaponenko Igor' Mikhajlovich[Am]

Markosjan David Egiazarovich[Am]

Voloshin Vsevolod Andreevich[Ru]

Dates

1997-09-20Published

1991-08-23Filed