FIELD: chemistry of metalloorganic compounds. SUBSTANCE: invention relates to the development of new metallocomplexes of pyridine-containing derivatives of porphyrazine exhibiting good solubility in organic solvents and can be used as dyes, catalysts, semiconductors for thin-film microelectronics, biologically active substances, photoactivating agents and so on. Invention relates to the synthesis of metallocomplexes of dipyridine-di-(tert. -butyl-benzo)-porphyrazine of the formula (I) where M - Cu, Co. Metallocomplexes of dipyridine-di-(tert.-butylbenzo)-porphyrazine are synthesized by interaction of 5/6-tert.-1,3,3-trichloroisoindolenine and 1-amino-3-imino-4/7-azaiso-indolenine in acetone in the presence of triethylamine, hydroquinone, sodium methylate and salts of corresponding metals. EFFECT: new compounds, improved method of synthesis. 1 cl, 3 dwg, 2 ex
Title |
Year |
Author |
Number |
DI(1,4-DITHIACYCLOHEXENE-DI(TERT-BUTYL-BENZO)PROPHYRAZINE AND METAL COMPLEXES THEREOF |
1994 |
- Kulinich V.P.
- Nikulina T.A.
- Majzlish V.E.
- Shaposhnikov G.P.
- Smirnov R.P.
|
RU2122547C1 |
METAL COMPLEXES OF DIHALOGEN-DI (TERT BUTYL) SUBSTITUTED PHTHALOCYANINES |
1993 |
- Majzlishch V.E.
- Kulinich V.P.
- Kolesnikova E.E.
- Sokolovskaja E.Eh.
- Shaposhnikov G.P.
- Smirnov R.P.
|
RU2093515C1 |
6/7-TERT-BUTYL-1,3,3-TRICHLOROISOINDOLENINE AS INTERMEDIATE PRODUCT FOR SYNTHESIS OF TERT-BUTYL-SUBSTITUTED PHTHALOCYANINES OR THEIR COMPLEXES |
1993 |
- Majzlish V.E.
- Kulinich V.P.
- Shaposhnikov G.P.
- Smirnov R.P.
- Sokolovskaja E.Eh.
|
RU2064928C1 |
6(7)-HALOGEN-1,3,3-TRICHLOROISOINDOLENINS AS INTERMEDIATE PRODUCTS FOR SYNTHESIS OF DIHALOGEN-SUBSTITUTED PHTHALOCYANINES OR THEIR COMPLEXES |
1993 |
- Majzlish V.E.
- Kulinich V.P.
- Shaposhnikov G.P.
- Kolesnikova E.E.
- Doroshina O.A.
- Smirnov R.P.
|
RU2074180C1 |
METHOD OF PREPARING ASYMMETRIC PORPHYRAZINS |
1997 |
- Kulinich V.P.
- Vasil'Ev S.I.
- Shaposhnikov G.P.
- Smirnov R.P.
|
RU2139289C1 |
TETRA-2,3-QUINOXALINOPORPHYRAZINE CHROMOCHLORIDE AS STABILIZING AGENT OF POLYVINYLCHLORIDE |
1993 |
- Smirnova G.N.
- Korzhenevskij A.B.
- Kojfman O.I.
- Markova L.V.
- Vostrukhin I.B.
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RU2074188C1 |
COMPOSITION FOR ANODIC ELECTRODEPOSITION (VARIANTS) |
1993 |
- Bespalova G.N.
- Larin A.N.
- Majzlish V.E.
|
RU2080346C1 |
TETRAFLUOROTETRAAZAPORPHYN |
1993 |
- Timofeeva S.V.
- Khelevina O.G.
- Berezin B.D.
|
RU2068846C1 |
54,56-INDIUM (III) CHLORO : 58,60-COBALT (II) OXO-6,11:19,24: :32,37:45,50-TETRAIMINO-5,52:13,18:20,31:39,44-TETRANITRILO- -OCTABENZO[C,G,E,P,U,Y,D,H] (1,10,19,28)-TETRAAZACYCLOHEXATRI- -ACONTINE SHOWING BACTERIOSTATIC EFFECT ON STAPHYLOCOCCUS AND ESCHERICHIA COLI |
1995 |
- Neustroeva N.R.
- Vorob'Ev Ju.G.
- Smirnov R.P.
- Kuznetsov O.Ju.
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RU2135500C1 |
TERT-BUTYL-(DIAMINO-β-ISOINDIGO) AS INTERMEDIATE PRODUCT FOR SYNTHESIS OF NOVEL MACROHETEROCYCLIC COMPOUNDS |
1995 |
- Neustroeva N.R.
- Vorob'Ev Ju.G.
- Smirnov R.P.
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RU2079494C1 |