FIELD: recovery and purification of rhenium. SUBSTANCE: rhenium is concentrated from solution in the form of sulfide. Dissolution of sulfide in hydrogen peroxide gives concentrated solution of rhenic acid. Rhenic acid is neutralized with ammonia and evaporated to dry ammonium perrhenate residue. In order to separate impurities, ammonium perrhenate is washed with ammonia at S: L ratio of 1:3 Pa. Treatment is carried out three of four times when cooling pulp to 0 C and separating flushing fluid by decantation. Pure ammonium perrhenate is reduced to metal. EFFECT: pure rhenium when isotope composition is retained at minium losses. 4 cl, 5 ex
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Authors
Dates
2001-08-10—Published
2000-02-28—Filed