FIELD: chemistry of metalloorganic compounds, chemical technology.
SUBSTANCE: invention relates to the improved method for preparing metal complexes of tetra-(5,8-dihydroxy-6-sulfo)-anthraquinone porphyrazine. Method is carried out by interaction of 2,3-dicarboxy-5,8-dimethoxy-6-sulfoanthraquinone with urea and the corresponding metal salt in the presence of chloride and ammonium molybdate and the following hydrolysis of the synthesized metal complex - tetra-(5,8-dimethoxy-6-sulfo)-anthraquinone porphyrazine by its treatment with sodium hydroxide. Proposed metal complexes can be used as catalysts, dyes and in other fields of science and technique.
EFFECT: improved preparing method.
2 cl, 3 dwg, 4 ex
Title | Year | Author | Number |
---|---|---|---|
2,3-DICARBOXY-5,8-DIMETHOXY-6-SULFOANTHRAQUINONE | 2005 |
|
RU2280027C1 |
METHOD FOR PREPARING METAL COMPLEX OF TETRA-(5,8-DIHYDROXY)-ANTHRAQUINONE PORPHYRAZINE | 2005 |
|
RU2277098C1 |
2,3-DICARBOXY-5,8-DIMETHOXYANTHRAQUINONE | 2005 |
|
RU2277084C1 |
2,3-DICARBOXY-6-SULFOANTHRAQUINONE | 2003 |
|
RU2246485C1 |
2,3-DICARBOXY-6-BROMO-7-METHOXYANTHRAQUINONE | 2005 |
|
RU2282617C1 |
2,3-DICARBOXY-6-(PARA-SULFOPHENYLENE)-ANTHRAQUINONE | 2003 |
|
RU2258065C2 |
2,3-DICARBOXY-5-ACETYLAMINO-7-METHOXYANTHRAQUINONE | 2009 |
|
RU2404961C1 |
2,3-DICARBOXY-6,7-DIMETHYLANTHRAQUINONE | 2004 |
|
RU2264380C1 |
TETRA-(5-OCTADECYLSULFAMOYL)ANTHRAQUINONE PORPHIRAZINES OF COPPER AND COBALT | 2008 |
|
RU2382788C1 |
2,3-DICARBOXY-5,6,8-TRIMETHYLANTHRAQUINONE | 2004 |
|
RU2264381C1 |
Authors
Dates
2006-07-20—Published
2005-03-18—Filed