FIELD: oxidation catalysts.
SUBSTANCE: invention relates to catalytic oxidation of saturated hydrocarbons with oxygen-containing gas. Process according to invention comprises contacting alkane with oxygen source in presence of catalyst including compound of general formula: , where R1 and R2 independently represent hydrogen atom, halogen atom, alkyl, aryl, cycloalkyl, hydroxy, alkoxy, carboxyl, alkoxycarbonyl, or acyl, or R1 and R2 can together form double bond or aromatic or non-aromatic ring; Y represents oxygen atom; X oxygen atom to hydroxyl group; m is integer 1 or 2; and n = 1. Process is conducted at 20 to 100°C. Advantageously, catalyst includes cocatalyst.
EFFECT: increased efficiency of catalytic system.
14 cl, 5 tbl, 6 ex
Title | Year | Author | Number |
---|---|---|---|
METHOD OF CONTINUOUS PREPARATION OF MIXTURE OF CYCLOALKANOL, CYCLOALKANOL AND CYCLOALKYL HYDROPEROXIDE | 1993 |
|
RU2116290C1 |
METHOD OF PREPARING C8-C12 CYCLOALKANOLS AND CYCLOALKANONES | 0 |
|
SU735588A1 |
PROCESS FOR PRODUCING CYCLOALKYL HYDROPERIOXIDES | 0 |
|
SU799325A1 |
METHOD OF PREPARING MIX CONTAINING CYCLIC UNSATURATED ALKANONE AND RELATED ALKANOL | 1992 |
|
RU2078753C1 |
0 |
|
SU144844A1 | |
METHOD OF PRODUCING 1,10-DECANDICARBOXYLIC ACID | 0 |
|
SU1171453A1 |
PROCESS FOR RECOVERING AND PURIFYING CYCLODODECANONE | 0 |
|
SU1133257A1 |
PEROXIDE COMPOUND STABILIZERS | 0 |
|
SU727562A1 |
METHOD OF OBTAINING CYCLODODECANOL AND CYCLODODECANONE | 0 |
|
SU622803A1 |
0 |
|
SU367078A1 |
Authors
Dates
2006-10-10—Published
2002-05-30—Filed