FIELD: chemistry of polymers, chemical technology.
SUBSTANCE: invention relates to a polymerization method of vinyl chloride monomer and optionally additional monomers by using a single or some organic peroxides. This method involves dosing at least one organic peroxide compound with half-time value from 0.0001 h to less 0.050 h at the polymerization point to the polymerization mixture. Dosing such initiating agent allows achievement of improving the polymerization rate regulation and higher rate of polymerization. By using this method vinyl chloride-base (co)polymer is prepared having less 50 mass parts of residual initiating agent per one million of mass parts of (co)polymer in measuring after polymerization and drying (co)polymer at 60°C for 1 h directly. (Co)polymer can be used in the molding process involving heating a (co)polymer to temperature exceeding its boiling point.
EFFECT: improved method for polymerization.
8 cl, 2 tbl
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POLYMERISATION METHOD FOR PRODUCING (CO) | 2004 |
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RU2260601C2 |
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Authors
Dates
2006-10-27—Published
2002-12-18—Filed