FIELD: process for continuous production of terephthalic or isophthalic acid by liquid phase oxidation of respective aromatic dialkyl hydrocarbon.
SUBSTANCE: in order to prepare reaction solvent at least part of mother liquor separated from produced acid is used. Oxidation catalyst concentration in mother liquor is measured beforehand and then oxidation catalyst concentration is continuously corrected due to direct control (regardless of water content). Predetermined quantities of solvent and aromatic hydrocarbon as raw material are continuously supplied to oxidizing reactor for oxidizing aromatic hydrocarbon by means of molecular oxygen. Water concentration in condensate returned from reactor is measured and controlled by means of discharged quantity of returned condensate for stabilizing water concentration in reaction system in order to obtain in the result dicarboxylic acid. Oxidation temperature is sustained stable due to controlling pressure; oxygen concentration in exhaust gas is sustained stable due to controlling feed of oxygen containing gas.
EFFECT: production of stable quality acid, rational consumption of resources, power and water for performing process.
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Authors
Dates
2008-01-10—Published
2006-03-02—Filed