METHOD FOR MOLYBDENUM EXTRACTION FROM PRODUCTS OF CATALYTICAL OLEFINE EPOXIDATION WITH ORGANIC PEROXIDES Russian patent published in 2009 - IPC C01G39/00 B01D11/04 B01J23/92 B01J23/28 

Abstract RU 2367609 C2

FIELD: chemistry.

SUBSTANCE: product of olefins epoxidation by organic peroxides are fractionated, the molybdenum-containing heavy fraction is washed from the oxidation by-products with caustic soda solution. The ligand is added to the obtained worked out alkali solution in order to bind the dissolved molybdenum to metal-organic complex with following mixture treatment with extragent at temperature equal to (1-1.18) Tcr and pressure equal to (1.36-3.4) pressure Pcr whereat Tcr is critical temperature and Pcr is critical pressure of the extragent. The molybdenum-containing compounds are precipitated from extract.

EFFECT: increased degree of molybdenum extraction (45,38% - 98,36%) from the worked out alkali solution independently of its composition.

1 dwg, 2 tbl, 6 ex

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RU 2 367 609 C2

Authors

Sagdeev Ajrat Adievich

Kajumov Rustem Aminovich

Petukhov Aleksandr Aleksandrovich

Gumerov Farid Mukhamedovich

Gabitov Farizan Rakibovich

Bilalov Timur Renatovich

Jakushev Il'Gizar Aljaltdinovich

Jarullin Rafinat Samatovich

Dates

2009-09-20Published

2007-10-29Filed