FIELD: chemistry.
SUBSTANCE: product of olefins epoxidation by organic peroxides are fractionated, the molybdenum-containing heavy fraction is washed from the oxidation by-products with caustic soda solution. The ligand is added to the obtained worked out alkali solution in order to bind the dissolved molybdenum to metal-organic complex with following mixture treatment with extragent at temperature equal to (1-1.18) Tcr and pressure equal to (1.36-3.4) pressure Pcr whereat Tcr is critical temperature and Pcr is critical pressure of the extragent. The molybdenum-containing compounds are precipitated from extract.
EFFECT: increased degree of molybdenum extraction (45,38% - 98,36%) from the worked out alkali solution independently of its composition.
1 dwg, 2 tbl, 6 ex
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Authors
Dates
2009-09-20—Published
2007-10-29—Filed