FIELD: chemistry.
SUBSTANCE: alkyd resin is obtained using wastes from the pulp and paper industry - distilled tall oil, its fatty acids, a mixture of tall oil with sunflower oil 4-5:1, by reacting them with glycerin or pentaerythritol. The acidic component used is a mixture of terephthalic acid with partially oxidised intermediate products of oxidation of p-xylene (mixture of organic acids, wastes from production of purified terephthalic acid). Production wastes contain the following in wt %: terephthalic acid - 80-85, p-toluic acid - 8-15, benzoic acid - up to 0.4; 4-carboxybenzaldehyde - up to 0.1, the rest-water. The reagents are loaded at the same time. The process is carried out at 250-255°C with release of reaction water through a fusion method.
EFFECT: method enables use of wastes from production of terephthalic acid, which reduces cost of the end product, obtaining alkyd resin in a single step, cutting overall synthesis time to 5 hours while preserving operational characteristics of the resin.
4 tbl
Title | Year | Author | Number |
---|---|---|---|
METHOD OF PRODUCING ALKYD RESIN | 2007 |
|
RU2375382C2 |
METHOD OF PRODUCING ALKYD RESINS | 2011 |
|
RU2454438C1 |
METHOD OF PRODUCING ALKIDE RESINS | 0 |
|
SU819123A1 |
METHOD OF PRODUCING PURE ISOPHTHALIC ACID AND BY-PRODUCTS FROM XYLENE FRACTIONS | 2009 |
|
RU2430911C2 |
METHOD FOR PREPARING ALKYDE RESIN | 2004 |
|
RU2266921C1 |
PROCESS FOR PRODUCING POLYESTER RESIN | 0 |
|
SU929660A1 |
METHOD FOR PREPARING ALKYD OLIGOMERS AND ALKYD LACQUER CONTAINING ALKYD OLIGOMER | 2005 |
|
RU2285705C1 |
METHOD OF ALKYD VARNISH PRODUCTION AND METHOD OF BULK COMPONENT FEED TO REACTOR WITH EXPLOSIVE MEDIUM, SUCH AS USED IN ALKYD VARNISH PRODUCTION | 2007 |
|
RU2348667C1 |
METHOD OF PRODUCING MODIFIED ALKIDE RESINS | 0 |
|
SU821450A1 |
ALKYD RESIN PRODUCTION PROCESS (OPTIONS) AND LACQUER MATERIAL BASED THEREON | 2004 |
|
RU2249017C1 |
Authors
Dates
2010-03-27—Published
2008-04-24—Filed