FIELD: chemistry.
SUBSTANCE: invention relates to high activity ZSM-48. Described is a catalyst composition for removing paraffin from hydrocarbon material which contains ZSM-48 crystals, having molar ratio of silicon dioxide to aluminium oxide equal to or less than 110, which does not contain inoculating crystals different from ZSM-48 and does not contain ZSM-50 crystals.The invention also describes a method of producing ZSM-48 crystals contained in the composition described above, involving: preparation of an aqueous mixture of silicon dioxide or silicate, aluminium oxide or aluminic acid, hexamethonium salts and an alkaline base, where the mixture has the following molar ratios: silicon dioxide: aluminium oxide 70-110, base: silicon dioxide 0.1-0.3 and hexamethonium salt: silicon dioxide 0.01-0.05, and heating the mixture while stirring for a period of time and temperature sufficient for formation of crystals. The invention also describes a method of removing paraffin from hydrocarbon material in the presence of the catalyst composition described above.
EFFECT: obtained ZSM-48 crystals and a composition based on said crystals exhibit high activity during removal of paraffin from hydrocarbon material.
29 cl, 1 tbl, 6 dwg, 15 ex
Title | Year | Author | Number |
---|---|---|---|
HYDROTREATMENT USING MIXTURES OF ZSM-48 CATALYSTS | 2006 |
|
RU2411999C2 |
COMPLEX HYDROTREATMENT WITH HIGH-EFFICIENCY CATALYSTS | 2008 |
|
RU2458969C2 |
HYDROGENATION CATALYSTS WITH BINDER THAT FEATURE SMALL SURFACE AREA | 2008 |
|
RU2480279C2 |
METHOD FOR HYDROTREATMENT IN ACIDIC MEDIUM FOR PRODUCING DIESEL FUEL | 2009 |
|
RU2509142C2 |
SYNTHESIS OF ZSM-48 CRYSTALS USING HETEROSTRUCTURE PRIMERS WHICH ARE NOT ZSM-48 | 2005 |
|
RU2361812C2 |
METHOD OF HYDROPROCESSING IN ACIDIC MEDIUM FOR PRODUCTION OF BASIC LUBRICATING OILS | 2009 |
|
RU2513105C2 |
HIGHLY-ACTIVE MOLECULAR SIEVES WITH STRUCTURE OF MTT TYPE | 2009 |
|
RU2501735C2 |
SYNTHESIS OF ZSM-5 CRYSTALS WITH IMPROVED MORPHOLOGY | 2013 |
|
RU2615689C2 |
MICROWAVE METHOD OF PRODUCING ZSM-12 ZEOLITE WITH MTW STRUCTURE | 2020 |
|
RU2740452C1 |
METHOD FOR SYNTHESIS OF ZEOLITE BETA USING DIETHYLENETRIAMINE | 2005 |
|
RU2378197C2 |
Authors
Dates
2011-02-20—Published
2006-12-12—Filed