FIELD: chemistry.
SUBSTANCE: method of producing phenol involves: a) oxidising cumene to obtain an oxidation product containing cumene hydroperoxide; b) splitting said oxidation product using an acid catalyst to obtain a splitting product containing phenol, acetone, hydroxyacetone and impurities; c) neutralising and washing said splitting product with an alkaline aqueous medium to form a neutralised splitting product; d) separating said neutralised splitting product via at least one distillation step to obtain at least a fraction containing phenol, and an aqueous fraction containing hydroxyacetone; e) treating said aqueous fraction with an oxidative reagent in the presence of a base to obtain an alkaline aqueous medium with low content of hydroxyacetone; f) recirculating at least a portion of said aqueous alkaline medium to the neutralisation and washing step (c) and g) extracting phenol from said phenol-containing fraction obtained at step d).
EFFECT: obtaining the desired product with efficient removal of the by-product - hydroxyacetone.
25 cl, 1 dwg, 2 ex
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Authors
Dates
2011-09-27—Published
2007-04-03—Filed