FIELD: chemistry.
SUBSTANCE: invention relates to radiation-curable coatings for use as primary coating for optical fibre. The radiation-curable primary coating composition contains: A) an oligomer; B) a first diluent monomer; C) a second diluent monomer; D) a photoinitiator; E) an antioxidant; and F) an adhesion promoter; wherein said oligomer is a product of reaction of: i) hydroxy ethyl acrylate; ii) aromatic isocyanate; iii) aliphatic isocyanate; iv) polyol; v) catalyst; vi) inhibitor. The oligomer has number-average molecular weight from at least 4000 g/mol to less than or equal to 15000 g/mol. The catalyst is selected from a group comprising dibutyl tin dilaurate, metal carboxylates, sulphonic acids, catalysts based on amines or organic bases, zirconium and titanium alkoxides, and ionic liquid salts of phosphonium, imidazolium and pyridinium. The solidified film of said radiation-curable primary coating composition has tan delta peak Tc from -25°C to -45°C and modulus of elasticity from 0.50 MPa to 1.2 MPa.
EFFECT: improved technological and operational characteristics of the coating.
7 cl, 4 tbl
Title | Year | Author | Number |
---|---|---|---|
D 1368 CR RADIATION-CURABLE PRIMARY COATING FOR OPTICAL FIBRE | 2007 |
|
RU2434914C2 |
RADIATION CURABLE PRIMARY COATINGS D1363 BT ON OPTICAL FIBRE | 2007 |
|
RU2435814C2 |
D1365 BJ RADIATION-CURABLE PRIMARY COATING FOR OPTICAL FIBRE | 2007 |
|
RU2436824C2 |
D 1369 D RADIATION-CURABLE SECONDARY COATING FOR OPTICAL FIBRE | 2007 |
|
RU2434915C2 |
SUPERCOATINGS D1381 FOR OPTIC FIBRE | 2007 |
|
RU2439113C2 |
PRIMARY COATING D1378 CA FOR OPTIC FIBRE HARDENED BY RADIATION | 2007 |
|
RU2439112C2 |
D 1364 BT SECONDARY COATINGS ON OPTICAL FIBRE | 2007 |
|
RU2472831C1 |
D 1370 R RADIATION-CURABLE SECONDARY COATING FOR OPTICAL FIBRE | 2007 |
|
RU2436822C2 |
D 1364 BT SECONDARY COATINGS ON OPTICAL FIBRE | 2007 |
|
RU2436823C2 |
OPTICAL FIBRE COATINGS CURABLE BY MONOCHROMATIC ACTINIC RADIATION | 2015 |
|
RU2714072C2 |
Authors
Dates
2012-01-10—Published
2007-12-13—Filed