FIELD: chemistry.
SUBSTANCE: invention relates to extraction of synthetic rubber from latex, particularly extraction of butadiene-(alpha-methyl)-styrene rubber. The method of extracting butadiene-(alpha-methyl)-styrene rubber from latex, which is stabilised with carboxylic acid soap and sodium salt of naphthalene sulphonic acid, is carried out using 0.5% sulphuric acid solution and a polyelectrolyte coagulant. The polyelectrolyte coagulant is an epichlorohydrin and dimethylamine copolymer obtained with molar ratio of reactants (1.03-1.10):1, or is a product of reaction of natural and organic compounds, having free amine groups, obtained by grafting a synthetic polymer to a carbohydrate backbone under the effect of an enzyme, said synthetic polymer forming side chains of the polyelectrolyte or poly(N[-3,5-ditertbutyl-4-oxybenzyl)ethylene amine. Latex is introduced into a serum medium which contains sulphuric acid and the polyelectrolyte coagulant at a rate which prevents formation lumps at temperature 20-40°C. Further, the formed rubber crumbs are separated from the serum, washed with water at pH 6.5-8.0 and the rubber crumbs are separated from the washing water, dehydrated, dried and briquetted.
EFFECT: higher extraction of rubber due to considerably low stickiness of the formed rubber crumbs.
1 tbl, 15 ex
Title | Year | Author | Number |
---|---|---|---|
METHOD FOR ISOLATION OF BUTADIENE-STYRENE (METHYL-STYRENE) AND BUTADIENE RUBBERS FROM LATEXES | 2000 |
|
RU2186072C1 |
METHOD OF RECOVERING SYNTHETIC RUBBERS FROM LATEXES | 2004 |
|
RU2253656C1 |
METHOD OF EMULSION RUBBER RECOVERY FROM LATEX | 2008 |
|
RU2351610C1 |
METHOD OF SEPARATING EMULSION POLYMERISATION SYNTHETIC RUBBER FROM LATEX | 2011 |
|
RU2489446C2 |
COAGULANT FOR SYNTHETIC RUBBER ISOLATION FROM LIQUID MEDIA | 2005 |
|
RU2281293C1 |
METHOD OF SALT-FREE CONGELATION OF RUBBER LATEXES | 2010 |
|
RU2442795C2 |
METHOD OF SALTLESS EXTRACTION OF OIL-FILLED BUTADIENE(METZYL)STYRENE RUBBER | 0 |
|
SU1541219A1 |
METHOD OF ISOLATION OF SYNTHETIC RUBBER FROM LATEX | 2002 |
|
RU2203287C1 |
METHOD OF ISOLATING SYNTHETIC RUBBERS FROM LATEXES | 1998 |
|
RU2140928C1 |
METHOD OF DISTRIBUTION OF EMULSION POLYMERIZATION RUBBER | 2016 |
|
RU2619703C1 |
Authors
Dates
2012-04-10—Published
2010-04-14—Filed