METHOD OF OBTAINING CATALYST FOR ISOTOPIC PROTIUM-DEUTERIUM EXCHANGE Russian patent published in 2013 - IPC B01J21/04 B01J23/50 B01J37/00 B22F9/24 B82B3/00 

Abstract RU 2490061 C2

FIELD: chemistry.

SUBSTANCE: invention relates to field of heterogenic catalysis, in particular, to method of obtaining catalyst for isotopic protium-deuterium exchange. Method includes obtaining metal nanoparticles in reduction of metal ions in inverse micellar solution, consisting of solution of metal salt, representing RhCl3 or RuOHCl3, SAS, representing sodium bis(2-ethylhexyl)sulfosuccinate, and non-polar solvent, isooctane, with further application on Al2O3 carrier, with silver nanoparticles being obtained by preparation of inverse micellar rhodium or ruthenium solutions with ratio of molar quantity of metal salt water solution to molar quantity of SAS in the range from 1:1 to 10:1; after that water-alcohol solution in quantity 5-50 wt % and ammonium solution in quantity 10-30 wt % are added, after which suspension is subjected to ultrasound processing, deaeration and exposure to γ-irradiation 60Co with dose from 1 to 40 kGy.

EFFECT: invention makes it possible to obtain catalyst which possesses high catalytic activity and is intended for work in temperature interval 77÷400 K.

2 cl, 4 tbl, 4 ex

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RU 2 490 061 C2

Authors

Antonov Aleksej Jur'Evich

Sergeev Mikhail Olegovich

Kuznetsov Mikhail Andreevich

Revina Aleksandra Anatol'Evna

Boeva Ol'Ga Anatol'Evna

Dates

2013-08-20Published

2011-07-14Filed