FIELD: power industry.
SUBSTANCE: method for preparation of spent nuclear fuel reprocessing solutions containing complexing agents for extraction of multivalent actinides at suppression of action of complexing agents consists in introduction to a solution of nitric-acid solutions of transient metals that fix complexing impurities better than plutonium does. As complexing agents, the solution can contain ethanedioic acid, mellitic acid and other polybasic acids and oxygen acids, DTPA and EDTA. As added binding agents, there used are nitric-acid solutions of molybdenum and/or zirconium, including spent nuclear fuel solution based on uranium-molybdenum alloys introduced in equimolar amounts or amounts close to them as to metal: complexing agent ratio.
EFFECT: invention allows extracting multivalent actinides from spent nuclear fuel solutions containing complexing agents applying non-destructive methods and without strong change of reagent medium.
5 cl
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Authors
Dates
2013-08-20—Published
2011-11-22—Filed