FIELD: chemistry.
SUBSTANCE: described is a method of obtaining a catalyst of an anionic ε-capralactam polymerisation by its direct interaction with an alkali metal compound in the presence of an aprotic solvent, removed after reaction completion, with a reaction being carried out at a temperature not lower than 60°C, with hydroxides or their combinations being applied as alkali metal compounds, and as active diluents - aliphatic hydrocarbons with the number of carbon atoms in the interval 5-9 or their mixtures, which form with a reaction product - water heterogenic azeotropes, removed in the course of conversion.
EFFECT: simplification and intensification of the catalyst obtaining process, increase of the catalyst activity.
2 cl, 1 tbl, 3 ex
Title | Year | Author | Number |
---|---|---|---|
0 |
|
SU1779245A3 | |
METHOD OF PRODUCING CATALYST FOR ANION POLYMERIZATION OF LACTAMS | 0 |
|
SU1754203A1 |
METHOD OF OBTAINING LACTAM POLYMERIZATION CATALYSTS | 0 |
|
SU1774940A3 |
CATALYSTS FOR PRODUCING MOULD POLYAMIDE, METHOD OF THEIR PRODUCTION AND THEIR APPLICATION | 2013 |
|
RU2640589C2 |
METHOD OF SYNTHESIS OF SODIUM CAPROLACTAMATE | 1991 |
|
RU2030401C1 |
NOVEL COMPOSITION FOR PRODUCING CAST POLYAMIDES | 2012 |
|
RU2596191C2 |
METHOD OF PREPARING SODIUM LACTAMOALUMINATES | 0 |
|
SU739070A1 |
METHOD FOR SURFACE CROSS-LINKING OF POLYMER PARTICLES | 2014 |
|
RU2671508C2 |
COMPOSITION FOR ANIONIC POLYMERISATION OF LACTAM | 2012 |
|
RU2608997C2 |
MOULDED POLYAMIDES, METHOD OF THEIR PRODUCTION AND THEIR APPLICATION | 2013 |
|
RU2631324C2 |
Authors
Dates
2014-07-20—Published
2012-11-08—Filed