FIELD: chemistry.
SUBSTANCE: invention relates to catalyst of hydrodesulphurisation of hydrocarbon raw material, consisting of heteropolycompound, containing as minimum one of the following heteropolyanions [Co2Mo10O38H4]6-, [Co(OH)6Mo6O18]3-, [Ni(OH)6Mo6O18]2-, [Ni2Mo10O38H4]6-, [P2Mo5O23]6-, [PMo12O40]3-, [SiMo12O40]4-, [Co(OH)6W6O18]3-, [PW12O40]3-, [SiW12O40]4-, [PMonW12-nO40]3- (wherein n=1-11), [PVnMo12-nO40](3+n)- (wherein n=1-4), and organic additive, representing compound, which contains, at least one carboxylic group and 2-20 carbon atoms, with content of organic additive constituting 5-15 wt % of catalyst weight, applied on porous carrier, with content in calcined at 550°C catalyst MoO3 and/or WO3 constituting 14.0-23.0 wt %, CoO and/or NiO - 4.0-6.5 wt %. The invention also relates to method for catalyst manufacturing and process of deep hydropurification of hydrocarbon raw material, consisting in conversion of oil distillates in presence of heterogeneous catalyst.
EFFECT: creation of novel hydrodesulphurisation catalyst.
8 cl, 2 tbl, 14 ex
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Authors
Dates
2016-01-20—Published
2014-01-29—Filed