FIELD: chemistry.
SUBSTANCE: method of preparing a catalyst is described, that comprises impregnating a carrier, which contains, wt %: aluminium borate Al3BO6 with the structure of norbergite - 5.0-25.0; sodium - not more than 0.03; γ-Al2O3 - the rest; aqueous solution of a bimetallic complex compound [Co (H2O)2(C6H5O7)]2[Mo4O11(C6H5O7)2] followed by drying. The proportions of the components are used such that the resulting catalyst contains, wt %: [Co (H2O)2(C6H5O7)]2[Mo4O11(C6H5O7)2] 33.0-43.0; carrier - the rest. The carrier contains, wt %: aluminium borate Al3BO6 with the structure of norbergite - 5.0-25.0; sodium - not more than 0.03; γ-Al2O3 - the rest. The carrier impregnation is used by a moisture capacity or from a solution excess. After impregnation, the catalyst is dried in air at the temperature of 100-200C°. The used conditions of preparation provide a catalyst having a specific surface of 130-180 m2/g, a pore volume of 0.35-0.65 cm3/g, the average pore diameter is 7-12 nm and is particles with a section in the form of a circle, trefoil or quatrefoil with a diameter of the circumscribed circle of 1.0-1.6 mm and the length of up to 20 mm.
EFFECT: producing a catalyst having maximum activity in target reactions occurring when hydrocarbon material is hydrotreated.
5 cl, 7 ex, 1 tbl
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Authors
Dates
2017-07-27—Published
2016-11-09—Filed