FIELD: measuring equipment.
SUBSTANCE: invention relates to measurement equipment and can be used in investigation of mass transfer processes and determination of diffusion coefficients of solvents in orthotropic capillary-porous materials in paper, light, construction and other industries. Method for determining diffusion coefficient of solvents in sheet orthotropic capillary-porous materials consists in the fact that in the investigated sheet material there is created a uniform initial content of a solvent distributed in a solid phase, then analyzed material is placed on a flat substrate from solvent-impermeable material, waterproofing upper surface of material, at the initial instant of time, the analyzed material is pulsed wetted along a straight line by a moving solvent source of constant efficiency in a given direction of the orthotropic material, electrodes of a galvanic converter are made in the form of rectilinear sections and are arranged on both sides of the pulse humidification line on straight lines parallel to the pulse humidification line located at the same specified distance from it, wherein pulse exposure is carried out with a solvent dose calculated by formula G≈2.3hLρ0Upxc, and time moments τ1 and τ2 fixed when equal galvanic converter signal values are achieved in vicinity of 0.9 Ep value, where h is thickness of analyzed material; L is pulse action pulse length; ρ0 is density of analyzed sample in dry state; Up is the equilibrium concentration of the solvent in the analyzed sample upon contact with saturated solvent vapor at a given temperature; xc – distance between electrodes of galvanic converter and line of exposure to solvent dose on surface of controlled article; Ep is galvanic converter signal value at concentration Up.
EFFECT: technical result is higher accuracy of control and reduced time and costs for research.
1 cl, 1 dwg, 1 tbl
Authors
Dates
2019-11-11—Published
2019-03-13—Filed