FIELD: chemistry.
SUBSTANCE: invention relates to two variants of a method for producing a perfluoroalkyne compound. According to one variant, the method includes reacting a perfluoroalkadiene compound in the presence of a catalyst in order to produce a perfluoroalkine compound, and satisfies one of the following conditions (C)-(F): (C) the catalyst includes at least one catalyst selected from a group including a fluorinated chromium oxide with a porosity of 0.08 ml/g or more, a fluorinated aluminium oxide with a porosity of 0.35 ml/g or more, and a fluorinated aluminosilicate with a porosity of 0.50 ml/g or more; (D) the catalyst contains a fluorinated metal oxide selected from a group including a fluorinated aluminium oxide and a fluorinated aluminosilicate with a porosity of 0.35 ml/g or more; (E) the catalyst contains a metal oxide fluorinated by interacting the metal oxide with at least one compound selected from a group including hydrofluorocarbon, hydrochlorofluorocarbon, and chlorofluorocarbon, wherein the metal of the metal oxide constitutes at least one element selected from a group including chromium, titanium, silicon, and zirconium; and (F) the catalyst includes one or multiple catalysts produced by fluorinating at least one metal oxide selected from a group including a chromium oxide with a porosity of 0.10 ml/g or more, an aluminium oxide with a porosity of 0.45 ml/g or more, and an aluminosilicate with a porosity of 0.50 ml/g or more. Invention also relates to a catalyst and to a method for producing a catalyst.
EFFECT: possibility of producing a perfluoroalkine compound with high selectivity at a high degree of conversion.
13 cl, 15 tbl, 3 ex, 3 dwg
Title |
Year |
Author |
Number |
METHOD FOR PRODUCING A PERFLUOROCYCLOALKENE COMPOUND |
2019 |
- Etou, Yuusuke
- Nakamura, Shingo
|
RU2779442C1 |
METHOD FOR PRODUCING HALOGENATED ALKENE COMPOUND AND FLUORINATED ALKYNE COMPOUND |
2020 |
- Etou, Yuusuke
- Nakamura, Singo
|
RU2793785C2 |
FIRE-SUPPRESSION COMPOSITIONS CONTAINING NON-SATURATED FLUOROCARBONS AND METHODS OF THEIR APPLICATION |
2006 |
- Nappa Mario Dzhozef
- Svearingen Ekaterina N.
- Sivert Allen Kapron
|
RU2434659C2 |
METHOD OF PRODUCING AND PURIFYING FLUOROHYDROOLEFINS |
2006 |
- Miller Ral'F N'Juton
- Nappa Mario Dzhozef
- Rao Vellijur Nott Mallikardzhuna
- Sivert Allen Kapron
|
RU2446140C2 |
METHOD OF SEPARATING FLUOROOLEFINS FROM HF BY LIQUID-LIQUID EXTRACTION |
2007 |
|
RU2448081C2 |
COMPOSITIONS CONTAINING FLUOROOLEFINS AND USE THEREOF |
2006 |
- Sivert Allen Kapron
- Nappa Mario Dzhozef
- Majnor Barbara Khehvilehnd
- Lek Tomas Dzh.
- Rao Vellijur Nott Mallikardzhuna
- Svearingen Ekaterina N.
- Shmitts Kornell'
- Mouli Nandini
- Perti Dipehk
|
RU2419646C2 |
METHOD OF PREPARING POLYFLUOROOLEFINS, FLUORINE-1- ETHYLCYCLOPENTENE AND PERFLUORO-2,3-DICHLOHEX-2-ENE OR PERFLUORO-4,5-DICHLOROOCT-4-ENE |
1991 |
- Karl Dzhordzh Krespan[Us]
|
RU2093502C1 |
NICKEL-SUBSTITUTED AND MIXED NICKEL- AND COBALT-SUBSTITUTED CHROMIUM OXIDE COMPOSITIONS, PREPARATION THEREOF, AND APPLICATION THEREOF AS CATALYSTS AND CATALYST PRECURSORS |
2003 |
- Nappa Mario Dzh.
- Rao Vellijur Nott Mallikardzhuna
- Rozenfel'D Kh. Dehvid
- Subramani Shekkhar
- Subramanian Munirpallam A.
- Sivert Allen K.
|
RU2318595C2 |
SATURATED LINEAR POLYFLUOROHYDROCARBONS, METHOD OF THEIR SYNTHESIS (VARIANTS), COMPOSITION FOR SOLID SURFACE CLEANSING |
1991 |
- Karl Dzhordzh Krespan[Us]
- V.N.Mallikarjuna Rao[Us]
|
RU2073664C1 |
COBALT-SUBSTITUTED CHROMIUM OXIDE COMPOSITIONS, PREPARATION THEREOF, AND APPLICATION THEREOF AS CATALYSTS AND CATALYST PRECURSORS |
2003 |
- Nappa Mario Dzh.
- Rao Vellijur Nott Mallikardzhuna
- Rozenfel'D Dehvid Kh.
- Subramani Shekkhar
- Subramanian Munirpallam A.
- Sivert Allen K.
|
RU2318594C2 |