FIELD: chemistry.
SUBSTANCE: invention relates to the technology of producing phosphorus-containing fertilizers. Disclosed is a method of processing apatite by opening with sulfuric acid to obtain phosphogypsum, which involves multistage washing of phosphogypsum with water. Phosphogypsum is washed with a solution of sulfuric acid with concentration of 20–40 g/dm3 at temperature of 70–90 °C and during blowing with air or live steam. Rare-earth elements are extracted from the obtained phosphate-sulfuric acid solution. Filtrate is returned to the head of apatite opening with sulfuric acid. At the next stage, phosphogypsum is washed with water to remove sulfuric acid. At the last stage, lime milk solution containing an equivalent amount of calcium oxide in relation to the amount of remaining sulfuric acid is treated in a countercurrent.
EFFECT: invention reduces costs for purification of phosphogypsum and extraction of rare-earth elements, simplifies the process of processing apatite and increases efficiency of the process.
3 cl, 3 dwg, 6 tbl, 7 ex
Title | Year | Author | Number |
---|---|---|---|
METHOD OF PROCESSING PHOSPHOGYPSUM | 2012 |
|
RU2525877C2 |
METHOD OF PROCESSING PHOSPHOGYPSUM FOR PRODUCTION OF CONCENTRATE OF RARE EARTH METALS AND GYPSUM | 2013 |
|
RU2520877C1 |
METHOD OF EXTRACTING RARE-EARTH METALS FROM PHOSPHOGYPSUM | 2012 |
|
RU2491362C1 |
METHOD OF EXTRACTING RARE-EARTH ELEMENTS FROM WET-PROCESS PHOSPHORIC ACID WHEN PROCESSING KHIBINY APATITE CONCENTRATES | 2011 |
|
RU2528692C2 |
METHOD FOR EXTRACTION OF RARE-EARTH ELEMENTS OF PHOSPHOGYPSUM | 1996 |
|
RU2104938C1 |
METHOD OF PROCESSING PHOSPHOGYPSUM | 2012 |
|
RU2504593C1 |
EXTRACTION OF RARE-EARTH ELEMENTS FROM HARD MATERIALS CONTAINING RARE-EARTH METALS | 2012 |
|
RU2519692C1 |
METHOD OF PROCESSING RARE-EARTH ELEMENTS CONCENTRATE | 2015 |
|
RU2595672C1 |
METHOD OF EXTRACTING RARE-EARTH ELEMENTS FROM HYDRATE-PHOSPHATE RESIDUES FROM APATITE PROCESSING | 2012 |
|
RU2524966C2 |
METHOD OF PROCESSING PHOSPHOGYPSUM WASTES TO OBTAIN A CONCENTRATE OF REE AND GYPSUM PLASTER | 2019 |
|
RU2708718C1 |
Authors
Dates
2025-03-12—Published
2023-12-01—Filed