FIELD: organic chemistry. SUBSTANCE: product: N-[(1-hydroxymethyl-2-hydroxy-2-n-nitrophenyl)ethyl]amines of the general formula n-NO2-C6-H4CH(OH)CH(NHR)CH2OH, where R - R=CH3, CH2Cl, CHCl2, CCl3, gross-formula is C11H14N2O5. Yield is 60%, m. p. is 126-127 C. Gross-formula is C11H13ClN2O5, yield is 46%, m. p. is 198-200 C. Gross-formula is C11H12Cl2N2O5, yield is 52%, m. p. is 136-138 C. Gross-formula is C11H11Cl3N2O5, yield is 70% , m. p. is 119-120 C. Reagent 1: 1-(p-nitrophenyl)-2-amino-1,3-propanediol. Reagent 2: chloroanhydride of acid. Reaction conditions: organic solvent, room temperature. Synthesized compounds are used in agriculture. EFFECT: improved method of synthesis, enhanced yields of products. 5 tbl
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Authors
Dates
1994-06-30—Published
1991-07-08—Filed