FIELD: solvents. SUBSTANCE: organohalide stock, more particularly perchloroethylene, trichloroethylene or difluorotrichloroethane is reacted with hydrogen fluoride in a liquid phase at elevated temperature and higher pressure in the presence of antimony pentachloride which further comprises 13-60 mol% tin tetrachloride, the catalyst being puliminarily treated with hydrogen fluoride at 20-150 C and a pressure of 0.1-2.3 MPa. EFFECT: more efficient process. 2 tbl
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METHOD FOR PRODUCTION OF DIFLUOROMETHANE | 1993 |
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Authors
Dates
1995-07-09—Published
1992-04-20—Filed