FIELD: preparation of fluoroplastic materials. SUBSTANCE: preparation of vinyl fluoride, difluoroethylene and trifluoroethylene is carried out by thermal dihydrofluorination of fluorine-containing ethanes in a chromium-nickel alloy reactor, its interval surface being preliminarily treated with pyrolysis products in the presence of steam. The starting ethanes to steam ratio is 2-3:1 at 650-700 C. Pyrolysis is then carried out at 700-900 C. The contact time is 0.05-2.5 s. EFFECT: more efficient preparation process. 4 tbl
Title | Year | Author | Number |
---|---|---|---|
PROCESS FOR PREPARING ETHANOL HALIDE | 1992 |
|
RU2039034C1 |
PROCESS FOR RECOVERY OF TETRAFLUOROETHYLENE FROM DIFLUOROCHLOROMETHANE PYROLYSIS PRODUCTS | 1986 |
|
RU2076853C1 |
METHOD OF PROCESSING POLYTETRAFLUOROETHYLENE | 2014 |
|
RU2559891C1 |
METHOD OF PREPARING 2-HYDROHEPTAFLUOROPROPANE OR MIXTURE OF 2-HYDROHEPTAFLUOROPROPANE AND OCTAFLUOROPROPANE | 1998 |
|
RU2134680C1 |
METHOD FOR PRODUCTION OF DIFLUOROMETHANE | 1993 |
|
RU2051140C1 |
METHOD OF SYNTHESIS OF OCTAFLUOROCYCLOBUTANE | 1994 |
|
RU2071509C1 |
METHOD OF RENDERING HARMLESS OF FLUOROCHLOROHYDRACARBONS | 1995 |
|
RU2091107C1 |
METHOD OF PREPARING 1-FLUOR-1,1-DICHLOROETHANE, 1,1-DIFLUORO 1-CHLOROETHANE, 1,1,1-TRIFLUOROETHANE AND REACTION UNIT DEVICE FOR CARRYING IT THROUGH | 1998 |
|
RU2160245C2 |
METHOD FOR PREPARING 1,1,1,2-TETRAFLUOROETHANE | 2003 |
|
RU2243961C1 |
METHOD OF SYNTHESIS OF PENTAFLUOROETHANE AND/OR HEXAFLUOROETHANE | 1995 |
|
RU2088564C1 |
Authors
Dates
1995-09-10—Published
1993-01-11—Filed