FIELD: chemical industry, more particularly preparation of inhibitor of polymerization of unsaturated hydrocarbons based on 2,2′,6,6′-tetramethyl-4- oxopiperidin-1-oxyl. SUBSTANCE: method comprises oxidizing 2,2′,6,6′-tetramethyl-4-oxopiperidine with organic hydroperoxide in the presence of variable valency metal compounds as catalyst. Method makes it possible to increase yield of the desired product and improve its inhibiting activity. EFFECT: more efficient preparation method. 5 cl, 7 ex, 2 tbl
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METHOD OF PREPARING POLYMERIZATION INHIBITOR OF UNSATURATED HYDROCARBONS | 1996 |
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METHOD OF INHIBITING PROCESS OF THERMOPOLYMERIZATION AND RESIN FORMATION OF UNSATURATED HYDROCARBONS | 1996 |
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METHOD OF INHIBITION OF DIOLEFINIC HYDROCARBON POLYMERIZATION PROCESS | 1996 |
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METHOD OF INHIBITING POLYMERIZATION OF VINYL AROMATIC HYDROCARBONS | 1996 |
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METHOD OF PREPARING 2,2′,6,6′-TETRAMETHYL-4-OXOPIPERIDINE | 1998 |
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METHOD FOR INHIBITION OF POLYMERIZATION PROCESS OF VINYLAROMATIC HYDROCARBONS | 2003 |
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METHOD OF LIQUID-PHASE OXIDATION OF HYDROCARBONS | 1996 |
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N-OXIDE DIMER 2,2,6,6-TETRAMETHYLPIPERIDYL-4-FULVEN AS INHIBITOR OF POLYMERIZATION OT VINYL MONOMER | 0 |
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Authors
Dates
1999-10-20—Published
1998-10-05—Filed