FIELD: chemical industry, more particularly preparation of organophosphorous compounds. SUBSTANCE: 2- chloro-2-alkenylphosphonic dichlorides of formula: RCH = CClCH2P(O)Cl2 wherein R is alkyl, are prepared by reaction of 2-alkyl- 1,1-dicyclopropane with phosphorus trichloride in the presence of equimolar amount of aluminium trichloride followed by treatment of reaction mixture with water in methylene chloride. EFFECT: shorter process time. 2 ex
| Title | Year | Author | Number |
|---|---|---|---|
| METHOD OF PREPARING 2-DICHLOROMETHYLENECYCLOHEXYLPHOSPHONIC ACID DICHLORIDE | 2003 |
|
RU2247728C1 |
| METHOD OF 3,3-DICHLORO-1-METHYLALLYLPHOSPHONIC ACID DICHLOROANHYDRIDE SYNTHESIS | 0 |
|
SU1735302A1 |
| PROCESS FOR PREPARING ALLYLPHOSPHONIC ACID DICHLOROANHYDRIDE | 0 |
|
SU1133277A1 |
| METHOD OF OBTAINING DICHLORANHYDRIDES OF ALKENYLPHOSPHORIC ACIDS | 0 |
|
SU1558919A1 |
| METHOD OF OBTAINING DICHLORANHYDRIDE-2-ALKOXYVINYLPHOSPHONIC ACIDS | 0 |
|
SU1105495A1 |
| METHOD OF OBTAINING ACID DICHLORIDE OF 1,1,2-TRICHLOR-2-ALKOXYETHYL PHOSPHONIC ACIDS | 0 |
|
SU1162810A1 |
| METHOD FOR PREPARING 7,7-DICHLOROBICYCLO[4,1,0]HEPTYL-2-PHOSPHONIC ACID DICHLOROANHYDRIDE | 2004 |
|
RU2266910C1 |
| METHOD OF OBTAINING 4-METHYL-2-OXO-2-CHLOR-1,2-OXAPHOSPHOLENE-3 | 2007 |
|
RU2340620C1 |
| METHOD FOR OBTAINING DICHLORO-SUBSTITUTED CYCLOPROPYLALKENYL(ALKYL) PHOSPHONIC OR THIOPHOSPHONIC CHLORIDES | 0 |
|
SU1659419A1 |
| METHOD OF OBTAINING ARYLDICHLOR OR DIARYLCHLORPHOSPHINES | 0 |
|
SU1576534A1 |
