FIELD: organic synthesis.
SUBSTANCE: invention relates to synthesis of organophosphorous compounds bearing P-C bond, in particular to preparation of novel 2-dichloromethylenecyclohexylphosphonic acid dichloride (formula I: 
comprising reaction of 2-alcoxy-7,7-dichlorobicyclo[4.1.0]heptane with phosphorus trichloride in presence of aluminum trichloride used at molar ratio 1:1:1 or 1:2:1, followed by treatment of resulting complex with water in dichloromethane.
EFFECT: increased choice of organophosphorous compounds for use as intermediates in organophosphorous synthesis.
4 ex
| Title | Year | Author | Number |
|---|---|---|---|
| METHOD FOR PREPARING 7,7-DICHLOROBICYCLO[4,1,0]HEPTYL-2-PHOSPHONIC ACID DICHLOROANHYDRIDE | 2004 |
|
RU2266910C1 |
| METHOD OF 3,3-DICHLORO-1-METHYLALLYLPHOSPHONIC ACID DICHLOROANHYDRIDE SYNTHESIS | 0 |
|
SU1735302A1 |
| METHOD OF PREPARING 2-CHLORO-2-ALKENYLPHOSPHONIC ACID DICHLORIDES | 1998 |
|
RU2140923C1 |
| PROCESS FOR PREPARING ALLYLPHOSPHONIC ACID DICHLOROANHYDRIDE | 0 |
|
SU1133277A1 |
| METHOD OF PRODUCING DICHLOROANHYDRITES OF ARYLTHIOPHOSPHONIC ACIDS | 0 |
|
SU1498772A1 |
| METHOD OF OBTAINING DIHALOGENANHYDRIDES OF 1-ALKYL-2-ALKOXYETHYLPHOSPHONIC ACIDS | 0 |
|
SU1154285A1 |
| METHOD FOR SYNTHESIS OF DICHLORANHYDRIDE OF 2-(2,3-DICHLOROPROPOXY)ETHENYL PHOSPHONIC ACID | 2008 |
|
RU2387662C1 |
| METHOD OF OBTAINING DIHALOGENANHYDRIDES OF 1-BROMIDE-2-ALKOXYETHENYLPHOSPHONIC ACIDS | 0 |
|
SU1142479A1 |
| METHOD OF 3-(O,O-DIALKYLPHOSPHORYL)-PROPANOIC ACID ESTERS SYNTHESIS | 0 |
|
SU1754720A1 |
| PROCESS FOR PREPARING DIARYLCHLOROPHOSPHINES | 0 |
|
SU1131881A1 |
