FIELD: chemical industry. SUBSTANCE: described is method of preparing di(1-ethyl-1- alkoxyaluminium 60) fullerenes of general formula I: wherein n is 1-6, R is Et, Bun and C60 is allotropic modification of carbon. Method comprises reacting fulleren 60 with excessive amount of 1-ethyl-1-alkoxy aluminium chloride of Et (RO) AlCl type and activated magnesium in the presence of titanocene chloride ((Cp2T;Cl2)) in argon atmosphere under normal conditions in solvents for 12-16 hours. Yield of final products is 48-72%. EFFECT: new organoaluminium compounds. 8 ex, 1 tbl
Title | Year | Author | Number |
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METHOD OF PREPARING DI(1-ETHYL-1-(DIALKYLAMINE)ALUMINIUM)) [60] FULLERENES | 1999 |
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METHOD OF PREPARING DI(ALUMINIUM DIETHYL) [60] FULLERENES | 1999 |
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METHOD OF PREPARING 1-ALKOXY-2,3-FULLERENE [60] ALUMACYCLOPROPANES | 1999 |
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METHOD OF PREPARING 1-ETHYL-2,3-FULLERENE [60] ALUMACYCLOPROPANES | 1999 |
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METHOD OF COMBINED SYNTHESIS OF 1,2-BIS-(DIETHYL-ALUMA)-1- METHYLENE-2-ALKYLETHANES AND 1,4-BIS-(DIETHYLALUMA)-1,4- DIALKYLIDENEBUTANES | 2001 |
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METHOD FOR PREPARING 1-ETHYL-3,3-DIALKYL-6,7-FULLERENO[60]CYCLOHEPTA-2-OX-1-ALANES | 2002 |
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METHOD OF PREPARING 1-(DIALKYLAMINO)-2- (TRIALKYLSILYL)ALUMACYCLOPROPANES | 1999 |
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Authors
Dates
2000-12-10—Published
1999-07-12—Filed