FIELD: organometal and fine syntheses. SUBSTANCE: method comprises reacting alpha- olefins with 1-(N,N-dialkylamine)-1-isobutyl-1-chloroalanes in the presence of zirconocene dichloride catalyst in boiling methylene chloride at 40 C for 8-12 h. Yield of desired products is 55-74%. EFFECT: more efficient preparation method. 1 tbl
Title | Year | Author | Number |
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METHOD OF COMBINED PREPARATION OF 1-ALKOXY-CHLORO-1-(n-ALKYL)ALANES AND 1- ALKOXY-1-CHLORO-1-(ISO-ALKYL)ALANES | 1999 |
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METHOD OF PREPARING 1-VINYL-1-METHYL-3-ALKYLSILACYCLOPENTANES | 2000 |
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METHOD OF PREPARING 1,2-BIS/(DIALKYLAMINE)ALUMA/CIS-1,2- DIPHENYL (ALKYL)ETHYLENES | 1996 |
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METHOD FOR PREPARING 1-ETHYL-3-METHYL-3-PHENYL-(ETHYL-, CYCLOPROPYL-)-4-ALKYLIDENECYCLOHEPTA-2-OXALANES | 2002 |
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METHOD OF PREPARING 1-(DIALKYLAMINO)-2-PHENYL (ALKYL)ALUMACYCLOPROPANES | 1996 |
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METHOD OF SYNTHESIS OF 1,3-DIALKYL-2-(N-PROPYL)-PROP-2Z-EN-1-OLS | 2001 |
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METHOD OF PREPARING 1-(DIALKYLAMINO)-2- (TRIALKYLSILYL)ALUMACYCLOPROPANES | 1999 |
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METHOD OF COMBINED SYNTHESIS OF 1-ETHYL-3,6-DIALKYLCYCLOHEPTAOXALANES AND 1-ETHYL-3,5-DIALKYLCYCLOHEPTAOXALANES | 2001 |
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RU2192423C1 |
CATALYST FOR PREPARING 1-ALKOXY-2-ARYLALUMACYCLOPROPANES | 1999 |
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RU2176547C2 |
METHOD OF JOINTLY PREPARING 1-ETHYL-3,3,6-TRIALKYLCYCLOHEPTAOXALANES AND 1- ETHYL- 3,3,5-TRIALKYLCYCLOHEPTAOXALANES | 2001 |
|
RU2197497C2 |
Authors
Dates
2001-02-10—Published
1999-05-12—Filed