FIELD: polymerization catalysts. SUBSTANCE: catalyst consists of nickel compound deposited on solvent-swelling polymer substrate in and organoaluminum compound as activator. Catalyst is distinguished by containing, as polymer substrate, reticularstructure carbochain rubber with swelling capacity 0.1 to 4.5 ml/g catalyst, aluminum-to-nickel molar ratio being 1-5 and content of nickel 0.2-2.2 wt %. Catalyst additionally contains waxy paraffin or olefin applied on the surface of catalyst in the form of strap. Catalyst can catalyze dimerization and oligomerization of not only pure C2-C6 olefins but also a variety of petroleumprocessing C2-C6 olefin fractions. EFFECT: simplified catalyst composition, increased productivity, and enabled catalysis of both olefin dimerization and oligomerization at good mechanical stability and chemical resistance. 2 cl, 1 tbl, 18 ex
Title | Year | Author | Number |
---|---|---|---|
OLEFIN DIMMER AND OLIGOMER PRODUCTION PROCESS | 2001 |
|
RU2184720C1 |
PROPYLENE TRIMER AND TETRAMER PRODUCTION PROCESS | 2001 |
|
RU2200725C1 |
METHOD OF OBTAINING OLEFIN HYDROCARBON | 0 |
|
SU1387345A1 |
METHOD OF OBTAINING N-BUTENE | 0 |
|
SU1356384A1 |
METHOD OF OBTAINING CATALYST FOR DIMERIZATION AND CODIMERIZATION OF OLEFINS | 0 |
|
SU1365431A1 |
METHOD OF OBTAINING OLEFIN HYDROCARBON | 0 |
|
SU1586113A1 |
METHOD OF OBTAINING OLEFIN HYDROCARBON | 0 |
|
SU1356383A1 |
METHOD FOR OBTAINING DIMERS OF C-C OLEFINS | 0 |
|
SU1664779A1 |
METHOD OF THE PREPARATION OF BUTENE-1 | 0 |
|
SU681036A1 |
METHOD OF OBTAINING OLEFIN HYDROCARBON | 0 |
|
SU544240A1 |
Authors
Dates
2003-04-20—Published
2001-08-24—Filed