METHOD OF CHROMATOGRAPHIC FRACTIONATION OF RARE-EARTH AND TRANSPLUTONIUM ELEMENTS Russian patent published in 2003 - IPC

Abstract RU 2211721 C2

FIELD: chromatographic fractionation of transplutonium and rare-earth elements. SUBSTANCE: method includes sorption on highly acid sulfacationite in hydrogen form; elution with solution of ammonium diethylenetriamino pentaacetate through layer of highly acid sulfacationite in form of ion of transition metal. Elution is carried out with solution of diethylenetriamino pentaacetate additionally containing nitrilotriacetate of alkali metal or ammonia. Used sulfacationite may be in form of ions of bivalent transition metals from group including Ni, Co, Cu, Zn, Cd, Pb, Fe. EFFECT: increased separation efficiency of promethium and samarium from yttrium with preserved separation efficiency of curium and americium from europium, accelerated process. 3 cl, 2 dwg

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RU 2 211 721 C2

Authors

Gelis V.M.

Kharitonov O.V.

Firsova L.A.

Chuveleva Eh.A.

Peshkov A.S.

Maslova G.B.

Svetlakov V.I.

Malykh Ju.A.

Aldoshin A.I.

Jakovlev N.G.

Dates

2003-09-10Published

2001-07-06Filed