FIELD: organic chemistry, chemical technology. SUBSTANCE: invention describes method for preparing polybenzimidazoles by polycondensation of equimolecular amounts of bis- hydroxamic acids of the general formula:
wherein R means
,
,
with bis-sulfamides of the formula:
wherein
means
,
,
wherein X means σ-bond,
, -O- in medium of high- boiling polar solvents at temperature 20-150 C for 8-10 h. Invention provides using bis-sulfamides instead aromatic tetraamines. EFFECT: improved preparing method. 2 cl, 2 tbl
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Authors
Dates
2004-02-27—Published
2002-05-16—Filed