FIELD: organic chemistry, chemical technology.
SUBSTANCE: invention relates to a method for preparing simple macroethers of sym.-triazine order - bis-[(4,6-disubstituted)-1,3,5-triazine-2-yl]-oxides of the general formula (I):
wherein R and R' are similar or different and mean OCH3, morpholine, piperidine or pyrrolidine residue. The corresponding [(4,6-disubstituted)-1,3,5-triazinyl-2]-trimethyl ammonium chloride in absolute acetone at 20-30 C is added to mixture of equimolar amounts of trimethylamine and glycine sodium salt followed by stirring at this temperature for 8-12 h. Method provides elevating yield of the end product and to simplify process due to reduced energy consumption and enhancing the technological effectiveness.
EFFECT: improved preparing method.
2 cl, 8 ex
Title | Year | Author | Number |
---|---|---|---|
METHOD FOR PREPARING SYMMETRICAL-TRIAZINE ORDER MACROETHERS | 2002 |
|
RU2230741C1 |
2,4-BIS-(MORPHOLYL)-6-β--OXYCARBONYLMETHYLOXY-SYMMETRICAL-TRIAZINE AS ANTIDOTE | 2003 |
|
RU2230064C1 |
2,4-DIMORPHOLYL-6-SUBSTITUTED SYMMETRICAL TRIAZINES AS GROWTH-STIMULATING AGENTS FOR WHEAT SEEDS | 2003 |
|
RU2232160C1 |
STIMULATOR OF WHEAT GROWTH | 2009 |
|
RU2411728C2 |
2-ALLYLAMINO-4,6-BIS-(ETHOXYCARBOXYLATOMETHYL-AMINO)-1,3,5-TRIAZINE AS EFFECTIVE MODIFYING AGENT-COHARDENING AGENT OF EPOXY OLIGOMERS IN COMPOSITES OF ANHYDRIDE HARDENING | 2000 |
|
RU2187505C2 |
1,3,5-TRIAZINE QUATERNARY TRIMETHYLAMMONIUM SALT AS INTERMEDIATE COMPOUND IN SYNTHESIS OF MODIFYING AGENT-COHARDENING AGENT OF EPOXYOLIGOMERS IN COMPOSITES OF ANHYDRIDE HARDENING | 2000 |
|
RU2187504C2 |
SUBSTITUTED TRIAZOLYL-1,3,5-TRIAZINES AS WHEAT GROWTH STIMULATING AGENTS | 2003 |
|
RU2230065C1 |
METHOD FOR INCREASING RESISTANCE OF SUNFLOWER TO HERBICIDAL ACTION | 2001 |
|
RU2199860C1 |
4,6-BIS-(MORPHOLYL)-2-[2'-ETHOXYACETYLTETRAZOLYL)-5'-YL]-1,3,5-TRIAZINE AS ANTIDOTE | 2004 |
|
RU2265604C1 |
METHOXY-4-MORPHOLYL-6-CARBOXYMETHYLTHIO-1,3,5-TRIAZINE AS ANTIOXIDANT | 2001 |
|
RU2203895C1 |
Authors
Dates
2004-08-20—Published
2002-11-15—Filed