FIELD: catalyst preparation methods.
SUBSTANCE: invention provides double metallocide catalyst containing (i) one or more double metallocide compounds of formula: Mx[M'x'(CN)y]2 wherein M represents metal selected from group including Zn(II), Fe(II), Ni(II), Mn(II), Co(II), Sn(II), Pb(II), Fe(III), Mo(IV), Mo(VI), Al(III), V(V), V(IV), Sr(II), W(IV), W(VI), Cu(II) and Cr(III); M represents metal selected from group including Fe(II), Fe(III), Co(II), Co(III), Cr(II), Cr(III), Mn(II), Mn(III), Ir(III), Ni(II), Rh(III), Ru(II), V(IV), and V(V); x, x', y and z each are integers selected so that double metallocide compound exhibits electric neutrality; (ii) one or more organic complex ligands other than (iii); and (iii) one or more phospholipids or amino acid derivatives, which can be used to prepare polyether-polyols via polyaddition of alkylene oxides to starting compounds with active hydrogen atoms. Catalyst preparation procedure of is likewise provided.
EFFECT: enlarged assortment of high-activity double metallocide catalysts.
7 cl, 4 ex
Title | Year | Author | Number |
---|---|---|---|
DOUBLE METAL CYANIDE CATALYSTS FOR PRODUCTION OF POLYETHERPOLYOLS | 2000 |
|
RU2235589C2 |
METHOD OF PREPARING DOUBLE METAL CYANIDE CATALYSTS | 2000 |
|
RU2264258C2 |
METHOD OF PREPARING DOUBLE METAL CYANIDE CATALYSTS | 2001 |
|
RU2284218C2 |
DOUBLE METAL CYANIDE CATALYSTS FOR PRODUCTION OF POLYETHERPOLYOLS | 2000 |
|
RU2248241C2 |
ZINC/METAL/COBALT HEXACYANIDE-BASED CATALYST FOR SYNTHESIS OF POLYETHER-POLYOLS AND A METHOD FOR PREPARATION THEREOF | 1998 |
|
RU2207189C2 |
DOUBLE METAL-CYANIDE CATALYST AND METHOD OF OBTAINING IT | 2003 |
|
RU2341328C2 |
METHOD FOR PRODUCING POLYETHER CARBONATE POLYOLS | 2014 |
|
RU2668974C2 |
DOUBLE METAL CYANIDE-BASED CATALYSTS FOR PRODUCTION OF POLYETHER(ESTER)POLYOLS | 2000 |
|
RU2254164C2 |
IMPROVED BINARY METALLOCYANIDE CATALYSTS AND METHOD OF PRODUCTION OF SUCH CATALYSTS | 1997 |
|
RU2173215C2 |
HIGH-ACTIVITY DOUBLE METAL CYANIDE CATALYSTS | 1997 |
|
RU2177828C2 |
Authors
Dates
2004-10-10—Published
2000-01-31—Filed