FIELD: organic chemistry, herbicides, agriculture.
SUBSTANCE: invention describes benzoylcyclohexanediones of the general formula (I):
wherein R1 means cycloalkoxy-group with 3-8 carbon atoms, cycloalkylalkoxy- or cycloalkenylalkoxy-group with 3-8 carbon atoms in cycloalkyl or cycloalkenyl moiety and with 1-6 carbon atoms in alkoxy-group, phenoxy-group, halogenalkoxy-group with 1-6 carbon atoms, halogenalkylthio-group with 1-6 carbon atoms, 2-tetrahydrofuranylmethoxy-group, 2-tetrahydropyranylmethoxy-group, -O-(CH2)m-O-(CH2)n-R2a wherein R2a means alkoxy-group with 1-6 carbon atoms or benzyl; R2, R3, R4 and R5 mean independently of one another hydrogen, halogen atom, methyl or alkylsulfonyl with 1-6 carbon atoms in alkyl; R6 means OR12 wherein R12 means hydrogen atom, benzoyl, benzoylmethyl; R7 means hydrogen atom, alkyl with 1-6 carbon atoms; L means alkylene chain with 1-6 carbon atoms; Y means bivalent fragment CHR7 or C(R7)2; Z means bivalent radical fragment CHR7 or C(R7)2; m = 1, 2 or 3; n = 0, 1, 2 or 3; v = 1; w = 0, 1 or 2 under condition L-R1 must not mean CH2-O-phenyl if R2 and R3 mean chlorine atom, and R4 and R5 mean hydrogen atom. Invention describes also a herbicide agent based on compound of the formula (I) and a method for control of weeds using compound of the formula (I), or herbicide agent. Compounds of the formula (I) elicit the excellent herbicide effect against broad spectrum of monocotyledonous and dicotyledonous weeds.
EFFECT: valuable herbicide properties of compounds.
8 cl, 6 tbl, 10 ex
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Authors
Dates
2004-10-10—Published
1999-09-09—Filed