FIELD: basic organic synthesis, chemical technology.
SUBSTANCE: invention relates to the improved method for isomerization reaction of pentane-hexane fraction with aim for preparing high-octane additive for gasoline. Pentane-hexane fraction is subjected for isomerization reaction in reaction-rectifying process using a low-temperature platinum-alumina catalyst. The parent raw is subjected for preliminary separation for pentane and hexane fractions. These fractions are subjected for separate isomerization that is carried out in vapor phase in reaction zone in bottom of reaction-rectifying column. Catalyst is placed under plates of zone and pressure in reaction zone in maintained in the range from 0.6 to 3.6 MPa, temperature - from 110.0oC to 200.0oC in the mole ratio hydrogen : hydrocarbons at inlet into column from 0.03:1 to 4:1. Method provides enhancing conversion of n-pentane, n-hexane and methylpentanes to high-octane isomers, elevating octane number of isomerizate and constructive simplifying the process.
EFFECT: improved preparing method.
1 dwg, 1 ex
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Authors
Dates
2005-03-20—Published
2003-12-29—Filed