FIELD: polymer materials.
SUBSTANCE: invention relates to compositions containing (i) elastomer sensitive to oxidative, thermal, dynamic, or light- and/or ozone-induced degradation and (ii), as stabilizer, at least one compound belonging to type of S-substituted 4-(3-mercaptosulfinyl-2-hydroxypropylamino)diphenylamine, as well as to a method for preventing decoloration of substrates coming into contact with elastomers and to a method for stabilizing elastomers consisting in introducing into the latter or coating them with at least one compound belonging to type of S-substituted 4-(3-mercaptosulfinyl-2-hydroxypropylamino)diphenylamine. Composition of stabilized elastomer comprises (a) natural-origin or synthetic elastomer sensitive to degradation as mentioned above and (b) stabilizer, in particular at least one compound having following general formula 1: [R-S(=O)mCH2-CH(OH)-CH2]n-N(R1)2-n-R2 (1), where R represents C4-C20-alkyl, hydroxy-substituted C4-C20-alkyl, phenyl, benzyl, α-methylbenzyl, α,α-dimethykbenzyl, cyclohexyl, or -(CH2)qCOOR3, and, when m=0, R can be and, when n=1 and R4 is hydrogen, can also be R2-R1N-CH2-CH(OH)-CH2-S(=O)m(CH2)x- or R2-R1N-CH2-CH(OH)-CH2-S(=O)m-CH2-CH2-(O-CH2-CH2)y-; R1 represents hydrogen, cyclohexyl, or C3-C12-alkyl; R2 represents group ; R3 C1-C18-alkyl; R4 hydrogen or CH2-CH(OH)-CH2-S(=O)m-R; X C1-C8-alkyl; Y C1-C8-alkyl; m=0 or 1, n=1 or 2, q=1 or q=2-6, and y=1 or 2. Compounds of formula 1 stabilize elastomers, especially low-colored ones, prevent oxidative, thermal, dynamic, or light- and/or ozone-induced degradation thereof, and prevent decoloration of substrates coming into contact with elastomers.
EFFECT: enlarged assortment of elastomer-conditioning reagents.
16 cl, 3 tbl, 6 ex
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Authors
Dates
2005-09-27—Published
2000-10-10—Filed