FIELD: organic chemistry, chemical technology, herbicides.
SUBSTANCE: invention relates to a new method for preparing derivative of pyridine of the formula [d]: wherein values of R1, R3 and R4 are given below. Method involves interaction of a new derivative of pyridone of the formula [a]: wherein R3 represent halogen atom, cyano-group or nitro-group; R4 represents hydrogen atom or halogen atom with derivative of α-diazoester of the formula [f]: -N2CHCOR1 [f] wherein R1 represents (C1-C6)-alkoxy-group, and this interaction is carried out in the presence of acid. Proposed method is suitable and profit method for preparing derivatives of pyridine of the formula [d] possessing with specific system of substitutes and eliciting the herbicide activity.
EFFECT: improved preparing method.
8 cl, 2 tbl, 16 ex
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Authors
Dates
2006-03-20—Published
2002-07-31—Filed