FIELD: organic chemistry, in particular formaldehyde production.
SUBSTANCE: claimed method includes oxidation of hydrocarbon-containing gas with oxygen-containing gas at elevated temperature and pressure followed by reaction mixture cooling and separation of target liquid product. As hydrocarbon-containing gas ethane-containing gas is used, including natural and associated gases containing not less than 10 % of ethane. Ethane-containing gas preliminary pressed up to 2-5 MPa and heated up to 280-450°C, and oxygen-containing gas, preliminary pressed up to pressure of ethane-containing gas or more are separately fed into blenders of arranged in tandem reaction zones up to oxygen content of 2-10 vol.%. Reaction mixture is continuously cooled through wall either directly in oxidation process or before feeding thereof in next reaction zone to temperature not more than 450°C. As oxygen-containing gas air, oxygen or oxygen-enriched air are used.
EFFECT: increased formaldehyde yield, simplified process, decreased energy consumption.
2 cl, 4 ex, 1 tbl, 1 dwg
Title | Year | Author | Number |
---|---|---|---|
METHANOL PRODUCTION METHOD AND INSTALLATION FOR IMPLEMENTATION OF THE METHOD | 2001 |
|
RU2200731C1 |
METHOD OF PRODUCING METHANOL AND APPARATUS THEREFOR | 2015 |
|
RU2568113C1 |
METHOD OF METHANOL PRODUCTION AND PLANT FOR PRODUCTION OF METHANOL | 2000 |
|
RU2162460C1 |
PROCESS OF PRODUCING LIQUID OXYGENATES VIA CONVERSION OF NATURAL GAS AND INSTALLATION TO IMPLEMENT THE SAME | 2005 |
|
RU2282612C1 |
METHOD OF OBTAINING GLYCOLIC ACID ETHERS | 2013 |
|
RU2538971C1 |
METHOD OF THERMAL OXIDATION OF WELL METHANE AND INSTALLATION TO THIS END | 2009 |
|
RU2415703C2 |
COMBINED PRODUCING METHOD OF ELECTRIC POWER AND LIQUID SYNTHETIC FUEL INCLUDED IN STEAM GAS PLANT | 2007 |
|
RU2356877C2 |
METHOD FOR THERMAL OXIDATION OF METHANE TO METHANOL | 2011 |
|
RU2455276C1 |
PLANT FOR UTILISATION OF LOW-PRESSURE NATURAL AND ASSOCIATED OIL GASES AND METHOD FOR USE THEREOF | 2015 |
|
RU2587736C1 |
METHOD FOR PRODUCTION OF METHANOL SOLUTION OF FORMALDEHYDE, C-C-ALCOHOLS AND SYNTHETIC DIESEL FUEL AND DEVICE | 2006 |
|
RU2318795C1 |
Authors
Dates
2006-09-20—Published
2005-02-24—Filed