RHENIUM OXIDE CATALYST FOR METATHESIS OF OLEFINIC HYDROCARBONS, METHOD OF PREPARATION THEREOF, AND A PROPYLENE SYNTHESIS PROCESS INVOLVING USE THEREOF Russian patent published in 2007 - IPC B01J23/36 B01J21/04 B01J27/12 B01J37/02 C07C6/04 

Abstract RU 2292951 C1

FIELD: petrochemical processes and catalysts.

SUBSTANCE: invention provides rhenium oxide catalyst on anion-containing gamma-alumina-based support: 0.1-10.0% Re2O3 and 0.2-4.0% fluorine based on the weight of alumina. Catalyst is prepared by impregnating alumina, including 0.2-4.0 wt % fluorine, with rhenium compound solution, drying resulting mass, and subjecting it to heat treatment in oxidative and/or inert medium at 600-900°C. Propylene synthesis process including metathesis of C2-C4-olefinic hydrocarbon blend or ethylene alone is also described.

EFFECT: increased catalytic activity and simplified technology.

7 cl, 2 tbl, 8 ex

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RU 2 292 951 C1

Authors

Bespalova Natal'Ja Borisovna

Maslobojshchikova Ol'Ga Vasil'Evna

Kozlova Galina Alekseevna

Dates

2007-02-10Published

2005-12-29Filed