FIELD: catalysts in petrochemical processes. SUBSTANCE: catalyst for vapor-phase epoxidation of olefins containing no allyl hydrogen with oxygen contains 1 to 25 wt % silver, promoting amount of alkali metal, the same of rhenium, 10 to 1000 ppm magnesium oxide (on conversion to Mg metal based on total weight of catalyst) and carrier consisting of alumina (85 wt %) and magnesium oxide (0.001 to 2 wt % on conversion to Mg metal). Catalyst was shown to preserve its selectivity much longer than catalysts containing rhenium but no additional magnesium on magnesium-containing carrier. EFFECT: increased lifetime. 14 cl, 3 tbl
Authors
Dates
1999-04-27—Published
1994-07-06—Filed