FIELD: hydrogenation-dehydrogenation catalysts.
SUBSTANCE: invention relates to production of alkylaromatic hydrocarbon dehydrogenation catalysts and can be employed in chemical and petrochemical industries. Catalyst according to invention comprising molybdenum oxide MoO2, ferrous oxide F2O3, cerium dioxide CeO2, and iron, potassium, calcium , and magnesium compounds is characterized by containing solid solution of potassium ferrites and, additionally, cesium and/or rubidium ferrites MFeO2 and M2Fe10O16, where M=K+Contains and/or Rb, and also ferrite Ca2(MgZn)1Fe2O3 Catalyst may be granulated in the form of trefoil with holes in each foil, which are shifted toward the center of granule, or it may be in the form of circle with three, four, or five internal spokes. Catalyst preparation process and a process of dehydrogenation of alkylaromatic hydrocarbons in presence of indicated catalyst are also described.
EFFECT: enabled preparation of strong catalyst showing high activity and selectivity, and ensuring reduced pressure in reactor owing to lowered hydraulic resistance.
11 cl, 4 tbl, 10 ex
Title | Year | Author | Number |
---|---|---|---|
CATALYST FOR DEHYDROGENATION OF OLEFIN AND ALKYLAROMATIC HYDROCARBONS | 2006 |
|
RU2308323C1 |
CATALYST FOR DEHYDRATION OF ALCYLAROMATIC HYDROCARBONS | 2007 |
|
RU2325229C1 |
CATALYST FOR DEHYDRATION OF ALKYLAROMATIC, ALKYLPYRIDINE AND OLEFIN HYDROCARBONS | 2018 |
|
RU2664124C1 |
CATALYST FOR DEHYDROGENATION OF ALKYLAROMATIC HYDROCARBONS | 1994 |
|
RU2076778C1 |
CATALYST FOR DEHYDROGENATION OF ALKYLAROMATIC HYDROCARBONS | 2000 |
|
RU2187364C2 |
CATALYZER FOR DEHYDROGENATION OF THE ALKYL-AROMATIC HYDROCARBONS | 2005 |
|
RU2285560C1 |
OLEFIN AND ALKYLAROMATIC HYDROCARBON DEHYDROGENATION CATALYSTS | 2004 |
|
RU2266785C1 |
CATALYST FOR DEHYDROGENATION OF ALKYL AROMATIC HYDROCARBONS | 2020 |
|
RU2726125C1 |
CATALYST FOR DEHYDROGENATING ALKYLAROMATIC HYDROCARBONS | 2012 |
|
RU2509604C1 |
ISOPRENE PRODUCTION PROCESS | 2006 |
|
RU2314282C1 |
Authors
Dates
2007-07-10—Published
2006-05-06—Filed