FIELD: industrial organic synthesis and catalysts.
SUBSTANCE: invention provides a method for processing methanol into dimethyl ether and liquid hydrocarbons, the latter being used as high-octane components of gasolines Ai-92, 95. Processing comprises contacting of raw material, in at least one step, in at least one reactor containing catalyst: Pentasil-type zeolite and binder, followed by cooling resulting products, condensation and separation thereof to isolate methanol conversion hydrocarbon gases, water, and desired products, after which cooled hydrocarbon gases are recycled to methanol conversion stage in at least one reactor. Catalyst is characterized by SiO2/Al2O3 molar ratio 20-100, content of sodium oxide not higher than 0.2%, and additionally contained silicon dioxide and zirconium dioxide at following proportions of components: 1.0-15.0% silicon dioxide, 1.0-5.0% zirconium dioxide, 20-70% zeolite, and binder - the balance.
EFFECT: increased yield of desired products and improved performance characteristics of catalyst.
4 cl, 5 tbl, 18 ex
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Authors
Dates
2008-01-20—Published
2006-06-19—Filed