FIELD: organic chemistry.
SUBSTANCE: claimed method includes interaction of octachlorocyclopentene with hydrogen fluoride or hexachlorocyclopentene and simultaneous interaction of formed octachlorocyclopentene with hydrogen fluoride. Process is carried out at elevated temperature (60-180°C) and pressure up to 25 kgf/cm2 in presence of catalyst of general formula SbFnCl5-n, wherein n = 1 or 2 (including fractional numbers), obtained in situ in reactor by feeding of gaseous hydrogen fluoride through layer of SbCl5.
EFFECT: high active catalyst, decreased equipment corrosion, increased product yield.
1 cl, 3 ex
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