FIELD: chemistry.
SUBSTANCE: description is given of a method of obtaining olefins. The method involves passing a mixture of a hydrocarbon and oxygen containing gas through a catalyst zone, which is capable of maintaining burning over the upper limit the inflammability of the fuel, with obtaining of the above mentioned olefin. The catalyst zone consists of at least, a first layer of catalyst and a second layer of catalyst, where the second catalyst layer is put in the process line after the first catalyst layer, has different content from the first layer and has general formula: M1 aM2 bM3 cOz, where M1 is chosen from IIA, IIB, IIIB, IVB, VB, VIB, VIIB groups of lanthanides and actinoides, M2 is chosen from IIA, IB, IIB, IIIB, IVB, VB, VIB groups, and M3 is chosen from IIA, IB, IIB, IIIB, IVB, VB, VIB and VIIIB groups, a, b, c and z represent atomic ratios of the M1, M2, M3 and O components respectively. The value of a lies in the interval from 0.1 to 1.0, the value of b lies in the interval from 0.1 to 2.0, the value of c lies in the interval from 0.1 to 3.0, and the value of z lies in the interval from 0.1 to 9.0. The catalyst zone has a perovskite type structure.
EFFECT: perfection of the method of obtaining olefins.
9 cl, 4 tbl, 1 dwg, 4 ex
Title | Year | Author | Number |
---|---|---|---|
METHOD OF OBTAINING OLEFINS | 2004 |
|
RU2338733C2 |
METHODS AND SYSTEMS FOR PRODUCING POLYATOMIC ALCOHOLS | 2007 |
|
RU2454391C2 |
METHOD AND DEVICE FOR DETERMINING REACTION DECAY IN HYDROCARBON CONVERSION PROCESS | 2001 |
|
RU2264433C2 |
ZIRCONIUM DIOXIDE EXTRUDATES | 2004 |
|
RU2337752C2 |
METHOD FOR CATALYTIC PARTIAL OXIDATION OF HYDROCARBONS | 1994 |
|
RU2137702C1 |
METHOD FOR PREPARING OLEFINS | 1999 |
|
RU2209202C2 |
FERRIERITE COMPOSITIONS FOR REDUCTION OF NO EMISSIONS DURING CRACKING PROCESS WITH FLUIDISED CATALYST | 2004 |
|
RU2365615C2 |
METHOD FOR PRODUCTION OF HYDROCARBON FUEL | 1993 |
|
RU2101324C1 |
AROMATIC COMPOUND ALKYLATION PROCESS | 2002 |
|
RU2354641C2 |
PLASMA REACTOR FOR CONVERSION OF GAS TO LIQUID FUEL | 2010 |
|
RU2530110C2 |
Authors
Dates
2008-06-27—Published
2004-05-12—Filed