FIELD: chemistry.
SUBSTANCE: method involves two stages: a) cooling of a liquid mixture containing bisphenol-A and water in a bisphenol-A chiller with bisphenol crystals formation in the liquid phase; b) separation of bisphenol-A crystals from the liquid phase; c) at least, partial separation the liquid phase into bisphenol-rich organic phase and water-rich phase; d) feeding of phenol and at least a part of the bisphenol-rich organic phase to the adduct followed by formation of phenol and bisphenol-A crystal adduct in a mother solution; e) separation of crystal adduct from the mother solution; g) contact of at least a part of the mother solution obtained at the stage e) with a catalyst of isomerisation of bisphenol-A isomers into bisphenol-A; and h) recycling of at least a part of the mother solution processed at the stage g) through the stage d).
EFFECT: improved purity and output of the composition.
12 cl, 2 dwg, 1 ex
Title | Year | Author | Number |
---|---|---|---|
METHOD OF PRODUCING DIPHENOL A | 2008 |
|
RU2451663C2 |
METHOD OF PRODUCING HIGH-PURITY BISPHENOL A AND PRODUCTION APPARATUS | 2007 |
|
RU2422429C2 |
METHOD OF PRODUCING BISPHENOL A | 2006 |
|
RU2419600C2 |
METHOD FOR PRODUCING OF BISPHENOL A | 2013 |
|
RU2619461C2 |
METHOD OF SYNTHESIS OF BISPHENOL-A | 1994 |
|
RU2119906C1 |
CIRCULATION FLOW DEHYDRATION IN BISPHENOL A OBTAINMENT | 2005 |
|
RU2392261C2 |
METHOD OF EXTRACTING PHENOL FROM PHENOL-CONTAINING STREAMS IN PRODUCTION OF BISPHENOL A | 2005 |
|
RU2401255C2 |
METHOD AND APPARATUS FOR EXTRACTING BISPHENOL A | 2006 |
|
RU2417213C2 |
SYNTHESIS OF BISPHENOL A WITH LOW ISOMERISATION | 2005 |
|
RU2402521C2 |
METHOD OF OBTAINING BISPHENOL-A | 2019 |
|
RU2799337C2 |
Authors
Dates
2008-08-10—Published
2003-11-12—Filed