FIELD: chemistry.
SUBSTANCE: present invention pertains to the method of producing linear styrene dimers (cis- and trans-1.3-diphenylbut-1-enes) through oligomerisation of styrene in the presence of zeolite catalyst in a solvent. The method is characterised by that, the catalyst used is ZSM-12 type zeolite in H-form, in quantity of 5-20 wt %. The reaction is carried out in nonane with ratio styrene:nonane = 1:2-4 (vol.) and 80-110°C temperature.
EFFECT: use of this method simplifies the method of producing linear styrene dimers.
1 tbl, 6 ex
Title | Year | Author | Number |
---|---|---|---|
METHOD OF PRODUCING LINEAR STYRENE DIMERS | 2007 |
|
RU2349568C1 |
METHOD OF CYCLIC STYRENE DIMERS PRODUCTION | 2007 |
|
RU2354638C1 |
METHOD OF CYCLIC STEROL DIMER PRODUCTION | 2007 |
|
RU2350592C1 |
METHOD OF LINEAR STEROL DIMER | 2007 |
|
RU2350591C1 |
METHOD FOR MAKING CYCLIC STYRENE DIMERS | 2007 |
|
RU2354639C1 |
METHOD FOR COMBINED SYNTHESIS OF LINEAR AND CYCLIC HOMO- AND CODIMERS OF STYRENE AND ALPHA-METHYLSTYRENE | 2010 |
|
RU2428407C1 |
METHOD FOR COMBINED SYNTHESIS OF LINEAR CYCLIC HOMO- AND CODIMERS OF STYRENE AND α-METHYLSTYRENE | 2010 |
|
RU2424221C1 |
PROCESS OF PRODUCING LINEAR STYRENE DIMMER (TRANS-1,3-DIPHENYLBUTENE-1) | 2006 |
|
RU2317284C1 |
METHOD OF OBTAINING LINEAR DIMERS OF α-METHYLSTYRENE | 2006 |
|
RU2327676C1 |
LINEAR ALPHA-METHYLSTYRENE DIMERS' PRODUCTION PROCESS | 2006 |
|
RU2312095C1 |
Authors
Dates
2009-03-20—Published
2007-08-29—Filed