FIELD: chemistry.
SUBSTANCE: invention refers to methods of gold and silver recovery from sulphide concentrates and industrial deposited concentrates. Method involves leaching gold-bearing and argentiferous concentrates with acid thiocarbamide liquors with the oxidiser added and extraction recovering noble metals from leaches. Extraction is preceded with adding thiocyanate ions to leaches in amount to ensure complete transferring thiocyanate gold and silver complexes into the organic phase. Extractant is mixed tributyl phosphate (TBP) and diphenylthiocarbamide (DPTC) in kerosene, containing TBP 1.5-2.0 mole/l and DPTC 0.015-0.022 mole/l. Gold and silver are re-extracted from the organic phase with the reducing agents precipitating noble metals within reduction process.
EFFECT: lower thiocarbamide loss at the stage of noble metal extraction from the leach.
9 cl, 1 tbl, 25 ex
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Authors
Dates
2009-04-10—Published
2007-07-11—Filed